Danford marshall space flight center, marshall space flight center, alabama april 1998. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. The unsolved problems 23 experimental 27 material 27 stress corrosion cracking samples 27 electrochemical tests samples 27 solutions 28 measurement techniques 29. Stress corrosion cracking scc near the fusion boundary of a 316ng stainless steel ss welded joint in hightemperature water was investigated with emphasis on the relation to the. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stresscorrosion cracking scc. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Service experience and current research, technical report afmltr67329, in proc. Strength effect in stress corrosion cracking of high. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Mechanisms of stresscorrosion cracking asm international. Note 1 the stress levels mentioned below and the test stresses mentioned in 6.
The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. The hrsgs receive hot exhaust gases from the primary gas turbines gts. Stress corrosion cracking of brass in nonammoniacal solutions 15 stress corrosion cracking of pure copper 21 summary of stress corrosion cracking studies. Determination of threshold stress intensity factor for. Overview of stress corrosion cracking scc in water systems. Haz microstructure produced during manual metal arc welding of grade 250 steel was simulated over a length of 35 mm of cnt specimens, using a. Stress corrosion cracking scc is the type of failure mechanism caused by a combination of environmental, material and stress conditions fig. The hydrogeninduced cracking and hydrogen induced stress corrosion cracking is not dealt with in this paper. Electrochemistry of stress corrosion cracking of brass. Standard test method for determining threshold stress.
Although the c692 test method was designed to evaluate stress corrosion cracking of austenitic stainless steel, it was modified to use carbon steel coupons to make a quick, direct comparison of corrosion under insulation of various products. Corrosionpedia what is stress corrosion cracking scc. Chloride stress corrosion cracking inspectioneering. The application of compressive stresses such as by shot peening or the use of coatings offers an effective means of minimizing or at least delaying stresscorrosion cracking. Four factors, are required before stress corrosion cracking can occur. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved.
Threshold stress intensity factor for stress corrosion cracking of heat affected zone haz of mild steel in caustic solution has been determined using circumferential notch tensile cnt technique. Stress corrosion cracking scc in boilers and cooling. The critical stress intensity for stresscorrosion cracking k1scc was determined by measuring the current flow from an external. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Stress corrosion cracking evaluation of candidate high. The presence of flaws that concentrate stress or crevices that alter. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress corrosion cracks which caused these service failures. Bolz institute for materials research, national bureau of standards, washington, d. It is generally considered the most complex of the failure modes since it can attack soft or hard parts.
Stress corrosion cracking occurs in metal only under the simultaneous, combined effects of the following factors. Effects of irradiation on intergranular stress corrosion cracking g. Fernandez, joseph rogelio, stress corrosion cracking evaluation of candidate high strength stainless steels for prestressed concrete 2011. Failure avoidance stress corrosion cracking of a platetype heat exchanger, materials performance, vol 38, 1999. Stress corrosion cracking industrial metallurgists. Environmental cracking refers to a corrosion cracking caused by a combination of conditions that can specifically result in one of the following form of corrosion damage.
Stress corrosion cracking has been most extensively studied in metals because of the need to prevent failure far below yield stress in highstrength alloys such as those used in the aero space industry. Recently, stress corrosion has also been experi mentally studied in many nonmetallic materials, such as. The resistance of metals to stress corrosion cracking is always less when tension is applied in a transverse direction. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. Bruemmer b a departments of nuclear engineering and materials science and engineering, university of michigan, ann arbor, mi 48109, usa b pacific northwest laboratory, richland, wa 993. Good practices and lessons learned international atomic energy agency vienna isbn 978920. In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in. Bales langley research center langley station, hampton, va. Stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. The stresscorrosion cracking of carbon steel in coc02h20. This type of failure is referred to as stress corrosion cracking scc.
K iscc and crack growth rates of solutionannealed and sensitized. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Stress corrosion cracking scc is the progressive cracking of metals and alloys caused by the combined effect of sccprone microstructure. Effects of irradiation on intergranular stress corrosion. Stresscorrosion cracking of highstrength aluminum alloys. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. To handle cracking in a practical context, critical stress intensities and corresponding growth rates are necessary for design purposes.
Stress corrosion cracking scc is definitely one of the. Stress corrosion cracking scc is a fracture process that involves the combined and simultaneous action of a tensile stress and a corrosive environment. Smallamplitude cyclic loading, well below that needed to produce fatigue crack growth, superimposed on sustained tensile loading was observed to significantly lower the apparent threshold for stress corrosion cracking in certain instances 7, 8. A simple approach to the determination of threshold stress. Standard classification of resistance to stresscorrosion. Effects of fluoride and other halogen ions on the external. Stresses that cause environmental cracking arise from residual cold work, welding, grinding, thermal. Part one covers the mechanisms of scc and hydrogen embrittlement, while the focus of part two is on methods of testing for scc in metals.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. For the susceptibility to stresscorrosion cracking, the directional variation can be appreciable and must be considered in the design of the fabricated hardware. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Stress corrosion cracking of stainless steel components in.
Iaea nuclear energy series technical reports stress corrosion cracking in light water reactors. The threshold stress intensity k iscc of stress corrosion cracking scc for 40crmo steel in 3. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. For this test program, the steel coupons were made from 16 gage, carbon steel which were cut to 7 x 2. Other documents, such as milhandbook5, milstd1568, nasc sd24, and msfcspec522a, should be consulted for design recommendations. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Threshold stress applied applied stress or load fracture stmts fig. This question has intrigued many people for more than a century. Stress corrosion cracking scc is produced by the simultaneous interaction of three essential factors. This mechanism is characterized by corrosion in the microscopic granular composition of a metals surface.
The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Stress corrosion cracking in a brewery paul mueller company. Temperature is a significant environmental factor affecting cracking. Estimates of the stress corrosion threshold for a specific service application must be determined for each alloy and heat treatment using a test piece, stressing procedure, and corrosive environment that are appropriate for the intended service. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. It is the least for the short transverse direction.
Comparative stress corrosion cracking and general corrosion resistance of annealed and hardened 440c stainless steelnew techniques in stress corrosion testing m. National aeronaut ics and space admln istrat ion for sale by the clearinghouse for federal scientific and technical information. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. This article discusses the intricacies associated with the determination of threshold stress intensity for stress corrosion cracking k iscc of narrow regions such as the sensitized microstructure of austenitic stainless steel and presents a simple approach to the accurate determination of k iscc of a sensitized stainless steel. Scc occurs when the tensile stress and a specific environment are able to cause failure by their combined action, but are insufficient to cause failure by either one acting alone. Net why normally ductile and strong alloys should fail in an essentially brittle manner when exposed to certain environments at relatively low stresses. Therefore, when the applied stress is lower than the creep threshold stress, the crack models at low temperatures such as the dugdales model3 can be directly employed consequently, the size of creep region r s takes a similar form as eq. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.